@Article{SilvaCCMRBSM:2022:InSuSn,
               author = "Silva, Elen Leal da and Cuņa, Andr{\'e}s and Cadorin, Martina and 
                         Marcuzzo, Jossano Saldanha and Radtke, Claudio and Baldan, 
                         Maur{\'{\i}}cio Ribeiro and Siqueli, Aline Castilho Rodrigues 
                         and Malfatti, C{\'e}lia de Fraga",
          affiliation = "{Universidad de La Rep{\'u}blica} and {Universidad de La 
                         Rep{\'u}blica} and {Universidade Federal do Rio Grande do Sul 
                         (UFRGS)} and {Instituto Nacional de Pesquisas Espaciais (INPE)} 
                         and {Universidade Federal do Rio Grande do Sul (UFRGS)} and 
                         {Instituto Nacional de Pesquisas Espaciais (INPE)} and {Instituto 
                         Nacional de Pesquisas Espaciais (INPE)} and {Universidade Federal 
                         do Rio Grande do Sul (UFRGS)}",
                title = "Influence of the Support and SnO2 Content on the Electrocatalytic 
                         Properties of PdSn/C Electrocatalysts for EOR in Alkaline Medium",
              journal = "Waste and Biomass Valorization",
                 year = "2022",
               volume = "13",
               number = "3",
                pages = "1705--1715",
                month = "Mar.",
             keywords = "Alkaline direct ethanol fuel cells, Biocarbon, Ethanol oxidation 
                         reaction, PdSn catalyst, Spectroelectrochemical analysis.",
             abstract = "An in-house synthesized activated biocarbon (aBC) and commercial 
                         Vulcan carbon (V) were studied as PdSn catalyst supports for the 
                         ethanol oxidation reaction (EOR) in an alkaline medium. The 
                         results obtained showed that the PdSn/V electrocatalyst presented 
                         much higher catalytic performance than the PdSn/aBC. These results 
                         can be associated with the fact that the catalyst particles in the 
                         PdSn/V electrocatalyst presented a higher SnO2 concentration 
                         compared to PdSn/aBC. The presence of SnO2 has an electronic 
                         effect that accelerates the adsorption of ethanol on the surface 
                         of Pd, thus enhancing the ethanol oxidation kinetics and 
                         contributing to a significant improvement in the PdSn/V catalytic 
                         activity. However, no significant differences were observed in the 
                         EOR mechanism.",
                  doi = "10.1007/s12649-021-01604-w",
                  url = "http://dx.doi.org/10.1007/s12649-021-01604-w",
                 issn = "1877-2641",
             language = "en",
           targetfile = "silva_2022_influence.pdf",
        urlaccessdate = "16 maio 2024"
}